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Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201106672
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dc.titleVersatile enantioselective [3+2] cyclization between imines and allenoates catalyzed by dipeptide-based phosphines
dc.contributor.authorHan, X.
dc.contributor.authorZhong, F.
dc.contributor.authorWang, Y.
dc.contributor.authorLu, Y.
dc.date.accessioned2014-06-23T05:53:57Z
dc.date.available2014-06-23T05:53:57Z
dc.date.issued2012-01-16
dc.identifier.citationHan, X., Zhong, F., Wang, Y., Lu, Y. (2012-01-16). Versatile enantioselective [3+2] cyclization between imines and allenoates catalyzed by dipeptide-based phosphines. Angewandte Chemie - International Edition 51 (3) : 767-770. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201106672
dc.identifier.issn14337851
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/77350
dc.description.abstractA fast one: The title reaction proceeds in the presence of 5 mol % of the catalyst 1, and is complete within an hour. The 2-alkyl- and 2-aryl-substituted 3-pyrroline products are obtained in good yield and with high enantioselectivity. The application of the method to the concise formal synthesis of (+)-trachelanthamidine is also demonstrated. Boc=tert- butoxycarbonyl, M.S.=molecular sieves, TBDPS=tert-butyldiphenylsilyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/anie.201106672
dc.sourceScopus
dc.subjectallenes
dc.subjectcycloadditions
dc.subjectheterocycles
dc.subjectnucleophilic catalysis
dc.subjectphosphines
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1002/anie.201106672
dc.description.sourcetitleAngewandte Chemie - International Edition
dc.description.volume51
dc.description.issue3
dc.description.page767-770
dc.description.codenACIEA
dc.identifier.isiut000299034200033
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