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|Title:||Thermal decomposition of isomeric nitropropenes: A photoelectron spectroscopic study|
|Authors:||Chin, W.S. |
|Citation:||Chin, W.S.,Mok, C.Y.,Huang, H.H. (1990-03-14). Thermal decomposition of isomeric nitropropenes: A photoelectron spectroscopic study. Journal of the American Chemical Society 112 (6) : 2053-2056. ScholarBank@NUS Repository.|
|Abstract:||The thermal decomposition of the three isomers of nitropropene has been investigated in a flow system at low pressures, by using the characteristic bands of the photoelectron spectra of the products for their identification. Of the three isomers, 1- and 2-nitropropene decomposed to give products analogous to those found in the thermolysis of nitrostyrenes, implying some similarities in mechanism. On the other hand, 3-nitropropene gave similar products as 3-propenyl nitrite, indicating the isomerization of the nitro compound to the nitrite form as a probable first step for decomposition.|
|Source Title:||Journal of the American Chemical Society|
|Appears in Collections:||Staff Publications|
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