Please use this identifier to cite or link to this item: https://doi.org/10.1021/ol0263999
Title: The first example of enantioselective allyl transfer from a linear homoallylic alcohol to an aldehyde
Authors: Loh, T.-P. 
Lee, C.-L.K.
Tan, K.-T. 
Issue Date: 22-Aug-2002
Citation: Loh, T.-P., Lee, C.-L.K., Tan, K.-T. (2002-08-22). The first example of enantioselective allyl transfer from a linear homoallylic alcohol to an aldehyde. Organic Letters 4 (17) : 2985-2987. ScholarBank@NUS Repository. https://doi.org/10.1021/ol0263999
Abstract: (Formula Presented) The first example of enantioselective linear homoallylic alcohol transfer reaction was revealed. In all cases, the whole rearrangement is thermodynamically favorable and a steric effect is the driving force of this reaction. The preservation of the stereocenter and olefin geometry together with the isolation of γ-adduct homoallylic alcohols in one isomeric form have warranted the proposed mechanism.
Source Title: Organic Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/77239
ISSN: 15237060
DOI: 10.1021/ol0263999
Appears in Collections:Staff Publications

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