Please use this identifier to cite or link to this item: https://doi.org/10.1039/b411653d
Title: Silicon-assisted propargylic transfer to aldehydes
Authors: Lee, K.-C.
Lin, M.-J.
Loh, T.-P. 
Issue Date: 7-Nov-2004
Citation: Lee, K.-C., Lin, M.-J., Loh, T.-P. (2004-11-07). Silicon-assisted propargylic transfer to aldehydes. Chemical Communications 10 (21) : 2456-2457. ScholarBank@NUS Repository. https://doi.org/10.1039/b411653d
Abstract: A new and efficient method of obtaining homopropargylic alcohols via homopropargylic transfer from the allenic alcohol to various aldehydes in the presence of Lewis acid catalysts is described; stereochemical studies have shown that this process is the first oxonium [3,3]-sigmatropic rearrangement of an allenic alcohol to a homopropargylic alcohol in the presence of aldehydes and Lewis acid.
Source Title: Chemical Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/76968
ISSN: 13597345
DOI: 10.1039/b411653d
Appears in Collections:Staff Publications

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