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|Title:||Silicon-assisted propargylic transfer to aldehydes|
|Citation:||Lee, K.-C., Lin, M.-J., Loh, T.-P. (2004-11-07). Silicon-assisted propargylic transfer to aldehydes. Chemical Communications 10 (21) : 2456-2457. ScholarBank@NUS Repository. https://doi.org/10.1039/b411653d|
|Abstract:||A new and efficient method of obtaining homopropargylic alcohols via homopropargylic transfer from the allenic alcohol to various aldehydes in the presence of Lewis acid catalysts is described; stereochemical studies have shown that this process is the first oxonium [3,3]-sigmatropic rearrangement of an allenic alcohol to a homopropargylic alcohol in the presence of aldehydes and Lewis acid.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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