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|Title:||Self-assembly of perfunctionalized β-cyclodextrins on a quartz crystal microbalance lor real-time chiral recognition|
|Citation:||Xu, C., Ng, S.C., Chan, H.S.O. (2008-08-19). Self-assembly of perfunctionalized β-cyclodextrins on a quartz crystal microbalance lor real-time chiral recognition. Langmuir 24 (16) : 9118-9124. ScholarBank@NUS Repository. https://doi.org/10.1021/la800761h|
|Abstract:||This study reports the development of novel chiral sensors based on the self-assembly of perfunctionalized β-cyclodextrins (&beta-CD) on a quartz crystal microbalance transducer for real time chiral recognition. Ten chiral sensors immobilized with mercaptyl perfunctionalized β-cyclodextrins were found to exhibit promising enantioselectivity in the gas phase. Well-defined sizes of molecular cavities of the modified β-CDs associated with cooperative weak interactions with the host molecules afforded enhanced chiral discrimination. This study contributes to the realization of novel chiral sensors applicable for real-time recognition and analysis of enantiomeric alcohols and lactates. © 2008 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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