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Title: Self-assembly of methacrylamides assisted by an interplay of N-H⋯O, C-H⋯O, C-H⋯π and π-π interactions
Authors: Venkataramanan, B.
Saifudin, M.-A.
Jagadese J, V. 
Suresh, V. 
Issue Date: 20-Aug-2004
Citation: Venkataramanan, B., Saifudin, M.-A., Jagadese J, V., Suresh, V. (2004-08-20). Self-assembly of methacrylamides assisted by an interplay of N-H⋯O, C-H⋯O, C-H⋯π and π-π interactions. CrystEngComm 6 : 284-289. ScholarBank@NUS Repository.
Abstract: Solid state self-assembly of methacrylamides (1-3) with intermolecular N-H⋯O and C-H⋯O hydrogen bonds are discussed. Interesting structures in the crystal lattice of 1 and 2 are ascribed to the aromatic surfaces that are orthogonal and twisted to each other along the hydrogen bonded chains. In addition, an interconnected network of face-to-face (π⋯π) and edge-to-face (C-H⋯π) interactions have been observed which are cooperative in nature. Compound 3 showed a staggered packing of adamantane groups along the H-bonded chains. In all three structures, the self-assembly was facilitated by strong hydrogen bonding, π⋯π interactions and packing forces involving bulky groups. © The Royal Society of Chemistry 2004.
Source Title: CrystEngComm
ISSN: 14668033
Appears in Collections:Staff Publications

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