Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0040-4020(97)00941-1
Title: Photoelectron spectroscopy of monocyclic olefins
Authors: Novak, I. 
Potts, A.W.
Issue Date: 27-Oct-1997
Citation: Novak, I., Potts, A.W. (1997-10-27). Photoelectron spectroscopy of monocyclic olefins. Tetrahedron 53 (43) : 14713-14718. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4020(97)00941-1
Abstract: We present He I photoelectron spectra (UPS) of several isomeric monocyclic trienes and dienes. The spectra were interpreted by semiempirical MO calculations and comparison with spectra of related compounds. The results suggest that in 1,5,9-cyclododecatriene the homoconjugative π,π-interactions are sensitive to E/Z molecular topology while in 1,9-cyclohexadecadienes they are not. We have analyzed both π-ionization energies and σ-onset energies in order to unravel relative importance of through-space and through-bond interactions. We propose a new trans rule for monocyclic olefins.
Source Title: Tetrahedron
URI: http://scholarbank.nus.edu.sg/handle/10635/76753
ISSN: 00404020
DOI: 10.1016/S0040-4020(97)00941-1
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