Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.tetlet.2006.11.019
Title: P-C Bond formation via direct and three-component conjugate addition catalyzed by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD)
Authors: Jiang, Z. 
Zhang, Y.
Ye, W.
Tan, C.-H. 
Issue Date: 1-Jan-2007
Citation: Jiang, Z., Zhang, Y., Ye, W., Tan, C.-H. (2007-01-01). P-C Bond formation via direct and three-component conjugate addition catalyzed by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD). Tetrahedron Letters 48 (1) : 51-54. ScholarBank@NUS Repository. https://doi.org/10.1016/j.tetlet.2006.11.019
Abstract: The direct addition of P(O)-H bonds (dialkyl phosphites and diphenyl phosphonite) across various activated alkenes was catalyzed effectively by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD). This is a mild, rapid and efficient protocol to generate P-C bonds. This simple procedure allows a series of dialkyl alkylphosphonates and trisubstituted phosphine oxides to be prepared in high yields. Further investigation resulted in a convenient one-pot, three-component reaction containing diphenyl phosphonite, malononitrile and an aldehyde. © 2006 Elsevier Ltd. All rights reserved.
Source Title: Tetrahedron Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/76727
ISSN: 00404039
DOI: 10.1016/j.tetlet.2006.11.019
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