Please use this identifier to cite or link to this item: https://doi.org/10.1021/ol200538d
Title: One-pot synthesis of hybrid macrocyclic pentamers with variable functionalizations around the periphery
Authors: Qin, B.
Sun, C.
Liu, Y.
Shen, J.
Ye, R.
Zhu, J.
Duan, X.-F.
Zeng, H. 
Issue Date: 6-May-2011
Citation: Qin, B., Sun, C., Liu, Y., Shen, J., Ye, R., Zhu, J., Duan, X.-F., Zeng, H. (2011-05-06). One-pot synthesis of hybrid macrocyclic pentamers with variable functionalizations around the periphery. Organic Letters 13 (9) : 2270-2273. ScholarBank@NUS Repository. https://doi.org/10.1021/ol200538d
Abstract: Chemical equations presented. Rather than four- or six-residue macrocylces, one-pot macrocyclization allows for the highly selective formation of five-residue macrocycles rigidified by intramolecular hydrogen bonds. Variable functionalizations around the pentameric periphery were achieved by reacting monomers with higher oligomers bearing different exterior side chains. The formation of these hybrid pentamers suggests a chain-growth mechanism for the one-pot macrocyclization where the successive addition of monomers onto higher oligomers is faster than those between two monomers or two higher oligomers. © 2011 American Chemical Society.
Source Title: Organic Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/76673
ISSN: 15237060
DOI: 10.1021/ol200538d
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

32
checked on Oct 17, 2018

WEB OF SCIENCETM
Citations

32
checked on Oct 9, 2018

Page view(s)

41
checked on Aug 17, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.