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|Title:||Nanosized Co- and Ni-Catalyzed ammonia borane for hydrogen storage|
|Citation:||He, T., Xiong, Z., Wu, G., Chu, H., Wu, C., Zhang, T., Chen, P. (2009-06-09). Nanosized Co- and Ni-Catalyzed ammonia borane for hydrogen storage. Chemistry of Materials 21 (11) : 2315-2318. ScholarBank@NUS Repository. https://doi.org/10.1021/cm900672h|
|Abstract:||A "co-precipitation" method was applied to introduce nanosized Co- and Ni-based catalysts to ammonia borane. It was observed that approximately 1 equiv. of hydrogen was evolved from the doped ammonia borane samples at a temperature as low as 59 °C. Moreover, the catalytic dehydrogenation did not present any induction period, undesirable byproduct borazine, or sample forming. Electron paramagnetic resonance (EPR) characterization revealed that Co in a partially reduced state is the active species in the catalytic dehydrogenation of ammonia borane. © 2009 American Chemical Society.|
|Source Title:||Chemistry of Materials|
|Appears in Collections:||Staff Publications|
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