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|Title:||Molecular recognition in the palladium complex promoted asymmetric synthesis of a keto-ester heterofunctionalized P-chiral phosphine|
|Authors:||Leung, P.-H. |
|Citation:||Leung, P.-H., Lang, H., White, A.J.P., Williams, D.J. (1998-09-04). Molecular recognition in the palladium complex promoted asymmetric synthesis of a keto-ester heterofunctionalized P-chiral phosphine. Tetrahedron Asymmetry 9 (17) : 2961-2964. ScholarBank@NUS Repository. https://doi.org/10.1016/S0957-4166(98)00322-X|
|Abstract:||A chiral organopalladium complex promoted asymmetric Diels-Alder reaction between 1-phenyl-3,4-dimethylphosphole and methyl-trans-4-oxo-2- pentenoate gives the corresponding keto-carboxylate heterofunctionalized P- chiral phosphine ligand in which the keto group is stereoselectively located in the exo position of the phosphanorbornene skeleton.|
|Source Title:||Tetrahedron Asymmetry|
|Appears in Collections:||Staff Publications|
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