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Title: Miscibility behavior of blends of poly(alkyl methacrylate)s with poly(p-methylstyrene-co-methacrylonitrile)
Authors: Chen, Junjie
Goh, S.H. 
Lee, S.Y. 
Siow, K.S. 
Issue Date: 1-Jan-1995
Citation: Chen, Junjie,Goh, S.H.,Lee, S.Y.,Siow, K.S. (1995-01-01). Miscibility behavior of blends of poly(alkyl methacrylate)s with poly(p-methylstyrene-co-methacrylonitrile). Journal of Applied Polymer Science 56 (7) : 761-767. ScholarBank@NUS Repository.
Abstract: The miscibility behavior of various poly(p-methylstyrene-co-methacrylonitrile) (pMSMAN)/poly(alkyl methacrylate)s blends was studied using differential scanning calorimetry. pMSMAN is miscible with poly(methyl methacrylate), poly(ethyl methacrylate), poly(n-propyl methacrylate), poly(isopropyl methacrylate), and poly(n-butyl methacrylate) over certain copolymer composition ranges, but is immiscible with poly(isobutyl methacrylate) and poly(n-amyl methacrylate). The width of the miscibility window decreases with increasing size of the pendant ester group of the poly(alkyl methacrylate), and is wider than that of the corresponding poly(p-methylstyrene-co-acrylonitrile) blend system. Various segmental interaction parameters are calculated using a binary interaction model.
Source Title: Journal of Applied Polymer Science
ISSN: 00218995
Appears in Collections:Staff Publications

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