Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.tetlet.2007.09.078
Title: Iodobenzene-catalysed iodolactonisation using sodium perborate monohydrate as oxidant
Authors: Liu, H.
Tan, C.-H. 
Issue Date: 12-Nov-2007
Citation: Liu, H., Tan, C.-H. (2007-11-12). Iodobenzene-catalysed iodolactonisation using sodium perborate monohydrate as oxidant. Tetrahedron Letters 48 (46) : 8220-8222. ScholarBank@NUS Repository. https://doi.org/10.1016/j.tetlet.2007.09.078
Abstract: A convenient approach has been developed for iodolactonisation using iodobenzene as catalyst. The active reagent was generated in situ with tetra-n-butylammonium iodide (TBAI) and hypervalent iodine reagent, diacetoxyiodobenzene (PIDA). PIDA, in turn, was generated in situ using a catalytic amount of iodobenzene with sodium perborate monohydrate as the stoichiometric oxidant. A variety of olefinic acids including δ-pentenoic acids, δ-pentynoic acids and δ-hexynoic acid gave high yields of lactones using this methodology. © 2007 Elsevier Ltd. All rights reserved.
Source Title: Tetrahedron Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/76403
ISSN: 00404039
DOI: 10.1016/j.tetlet.2007.09.078
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

48
checked on Aug 20, 2018

WEB OF SCIENCETM
Citations

48
checked on Aug 20, 2018

Page view(s)

44
checked on May 18, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.