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|Title:||Highly selective chromium(III) ethylene trimerization catalysts with [NON] and [NSN] heteroscorpionate ligands|
|Authors:||Jun, Z. |
|Citation:||Jun, Z., Braunstein, P., Hor, T.S.A. (2008-09-08). Highly selective chromium(III) ethylene trimerization catalysts with [NON] and [NSN] heteroscorpionate ligands. Organometallics 27 (17) : 4277-4279. ScholarBank@NUS Repository. https://doi.org/10.1021/om8005239|
|Abstract:||Cr(III) complexes with [NON] and [NSN] heteroscorpionate ligands derived from bis(pyrazol-l-yl)methane have been prepared, which are active for ethylene trimerization to 1-hexene with high selectivity. Structural studies have established the coordination of the ether or thioether pendant group, which leads to a bicyclic metallaheterocycle flanked by pyrazoyl rings. © 2008 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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