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https://doi.org/10.1002/chem.201103136
| Title: | Highly enantioselective assembly of functionalized tetrahydroquinolines with creation of an all-carbon quaternary center |
| Authors: | Tan, H.R. Ng, H.F. Chang, J. Wang, J. |
| Keywords: | asymmetric synthesis cascade reactions organocatalysis tetrahydroquinolines thioureas |
| Issue Date: | 26-Mar-2012 |
| Citation: | Tan, H.R., Ng, H.F., Chang, J., Wang, J. (2012-03-26). Highly enantioselective assembly of functionalized tetrahydroquinolines with creation of an all-carbon quaternary center. Chemistry - A European Journal 18 (13) : 3865-3870. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201103136 |
| Abstract: | A Mannich-Michael combo: An efficient and highly enantioselective cascade process by H-bonding catalysis for the synthesis of functionalized tetrahydroquinolines has been developed. An indane amine-thiourea small molecule has been discovered to catalyze this process in high yields and with good diastereomeric ratios and excellent enantioselectivities (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Source Title: | Chemistry - A European Journal |
| URI: | http://scholarbank.nus.edu.sg/handle/10635/76305 |
| ISSN: | 09476539 |
| DOI: | 10.1002/chem.201103136 |
| Appears in Collections: | Staff Publications |
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