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https://doi.org/10.1021/ol202555v
| Title: | Highly enantioselective and regioselective substitution of morita-baylis-hillman carbonates with nitroalkanes | Authors: | Chen, G.-Y. Zhong, F. Lu, Y. |
Issue Date: | 18-Nov-2011 | Citation: | Chen, G.-Y., Zhong, F., Lu, Y. (2011-11-18). Highly enantioselective and regioselective substitution of morita-baylis-hillman carbonates with nitroalkanes. Organic Letters 13 (22) : 6070-6073. ScholarBank@NUS Repository. https://doi.org/10.1021/ol202555v | Abstract: | A highly enantioselective and regioselective substitution reaction of the Morita-Baylis-Hillman (MBH) carbonates with nitroalkanes catalyzed by a quinidine-derived tertiary amine-thiourea catalyst has been developed. The described method, which is different from most organocatalytic allylic substitutions of the MBH adducts to date, represents a novel approach to regioselectively functionalize the MBH adducts. © 2011 American Chemical Society. | Source Title: | Organic Letters | URI: | http://scholarbank.nus.edu.sg/handle/10635/76304 | ISSN: | 15237060 | DOI: | 10.1021/ol202555v |
| Appears in Collections: | Staff Publications |
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