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|Title:||Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex|
|Source:||Lu, J., Ji, S.-J., Teo, Y.-C., Loh, T.-P. (2005-01-06). Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex. Organic Letters 7 (1) : 159-161. ScholarBank@NUS Repository. https://doi.org/10.1021/ol047711c|
|Abstract:||(Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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