Please use this identifier to cite or link to this item:
|Title:||Fluorous oxime palladacycle: A precatalyst for carbon-carbon coupling reactions in aqueous and organic medium|
|Citation:||Susanto, W., Chu, C.-Y., Ang, W.J., Chou, T.-C., Lo, L.-C., Lam, Y. (2012-03-16). Fluorous oxime palladacycle: A precatalyst for carbon-carbon coupling reactions in aqueous and organic medium. Journal of Organic Chemistry 77 (6) : 2729-2742. ScholarBank@NUS Repository. https://doi.org/10.1021/jo202482h|
|Abstract:||To facilitate precatalyst recovery and reuse, we have developed a fluorous, oxime-based palladacycle 1 and demonstrated that it is a very efficient and versatile precatalyst for a wide range of carbon-carbon bond formation reactions (Suzuki-Miyaura, Sonogashira, Stille, Heck, Glaser-type, and Kumada) in either aqueous or organic medium under microwave irradiation. Palladacycle 1 could be recovered through F-SPE in various coupling reactions with recovery ranging from 84 to 95% for the first cycle. Inductively coupled plasma optical emission spectrometry (ICP-OES) analyses of the Pd content in the crude product from each class of transformation indicated extremely low levels of leaching and the palladacycle could be reused four to five times without significant loss of activity. © 2012 American Chemical Society.|
|Source Title:||Journal of Organic Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Oct 18, 2018
WEB OF SCIENCETM
checked on Oct 10, 2018
checked on Feb 25, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.