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|Title:||Fluorinated aromatic ketones as nucleophiles in the asymmetric organocatalytic formation of C-C and C-N bonds: A facile route to the construction of fluorinated quaternary stereogenic centers|
|Authors:||Zhao, Y. |
quaternary stereogenic center
|Citation:||Zhao, Y., Pan, Y., Liu, H., Yang, Y., Jiang, Z., Tan, C.-H. (2011-03-21). Fluorinated aromatic ketones as nucleophiles in the asymmetric organocatalytic formation of C-C and C-N bonds: A facile route to the construction of fluorinated quaternary stereogenic centers. Chemistry - A European Journal 17 (13) : 3571-3574. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201003761|
|Abstract:||Highly enantioselective Mannich and α-amination reactions have been successfully developed using α-fluorinated aromatic ketones as fluorocarbon nucleophiles in the presence of a bicyclic chiral guanidine (see scheme; Ms=methanesulfonyl). This method is a simple and efficient approach to the construction of fluorinated quaternary stereogenic centers. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.|
|Source Title:||Chemistry - A European Journal|
|Appears in Collections:||Staff Publications|
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