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|Title:||Five-fold-symmetric macrocyclic aromatic pentamers: High-affinity cation recognition, ion-pair-induced columnar stacking, and nanofibrillation|
|Citation:||Ren, C., Maurizot, V., Zhao, H., Shen, J., Zhou, F., Ong, W.Q., Du, Z., Zhang, K., Su, H., Zeng, H. (2011-09-07). Five-fold-symmetric macrocyclic aromatic pentamers: High-affinity cation recognition, ion-pair-induced columnar stacking, and nanofibrillation. Journal of the American Chemical Society 133 (35) : 13930-13933. ScholarBank@NUS Repository. https://doi.org/10.1021/ja206457b|
|Abstract:||Described in this study is a conceptually new class of five-fold-symmetric cavity-containing planar pentameric macrocycles with their interior decorated by five convergently aligned, properly spaced carbonyl oxygen atoms. These cation-binding oxygens enclose a hydrophilic lumen of 2.85 Å in radius and thus display high-affinity binding toward alkali metal cations, and possibly many other cations, too. Arising from their high-affinity recognition of metal ions, these planar macrocycles form cation- or ion-pair-induced one-dimensional columnar aggregates, and subsequently fascinating fibrillation results. © 2011 American Chemical Society.|
|Source Title:||Journal of the American Chemical Society|
|Appears in Collections:||Staff Publications|
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