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https://doi.org/10.1021/ja1106282
Title: | Enantioselective [3 + 2] cycloaddition of allenes to acrylates catalyzed by dipeptide-derived phosphines: Facile creation of functionalized cyclopentenes containing quaternary stereogenic centers | Authors: | Han, X. Wang, Y. Zhong, F. Lu, Y. |
Issue Date: | 16-Feb-2011 | Citation: | Han, X., Wang, Y., Zhong, F., Lu, Y. (2011-02-16). Enantioselective [3 + 2] cycloaddition of allenes to acrylates catalyzed by dipeptide-derived phosphines: Facile creation of functionalized cyclopentenes containing quaternary stereogenic centers. Journal of the American Chemical Society 133 (6) : 1726-1729. ScholarBank@NUS Repository. https://doi.org/10.1021/ja1106282 | Abstract: | A new family of dipeptide-based chiral phosphines was designed and prepared. d-Thr-l-tert-Leu-derived catalyst 4c promoted [3 + 2] cycloaddition of allenoates to α-substituted acrylates in a regiospecific and stereoselective manner, furnishing functionalized cyclopentenes with quaternary stereogenic centers in high yields and with excellent enantioselectivities. © 2011 American Chemical Society. | Source Title: | Journal of the American Chemical Society | URI: | http://scholarbank.nus.edu.sg/handle/10635/76095 | ISSN: | 00027863 | DOI: | 10.1021/ja1106282 |
Appears in Collections: | Staff Publications |
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