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|Title:||Direct white light phosphor based on metallorganic coordination extended networks for UV-light-emitting diodes|
|Source:||Liu, R.-S., Drozd, V., Bagkar, N., Shen, C.-C., Baginskiy, I., Chen, C.-H., Tan, C.H. (2008). Direct white light phosphor based on metallorganic coordination extended networks for UV-light-emitting diodes. Journal of the Electrochemical Society 155 (6) : P71-P73. ScholarBank@NUS Repository. https://doi.org/10.1149/1.2898188|
|Abstract:||We report the synthesis of single crystals of a metallorganic coordination compound, [Zn2 Cl4 (μ-bipy) 2], where bipy is 4, 4′ -trimethylene bipyridine, which is capable of producing white light as a single component. The coordination compound was crystallized by the hydrothermal synthesis of zinc chloride and bipy ligand, and the structure was determined by single-crystal x-ray diffraction refinement. The [Zn2 Cl4 (μ-bipy) 2] coordination complex crystallizes into a monoclinic crystal system in the P 21 /m space group. The coordination compound is a distinct single-component, white-light-emitting phosphor upon excitation by UV-light-emitting diodes. The internal quantum efficiency was found to be 32%. The crystal structure and photoluminescence properties of the coordination polymer are discussed. © 2008 The Electrochemical Society.|
|Source Title:||Journal of the Electrochemical Society|
|Appears in Collections:||Staff Publications|
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