Conformation preferences of 1,1′bis(1-amino-4,4-dicyclopropyl-2,3-diaza-1,3-butadienyl)
Lam, Y. Ma, N.L. Liang, E.
Ma, N.L.
Liang, E.
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Abstract
The reaction of dicyclopropyl ketone with hydrazine sulfate and sodium cyanide afforded 1,1′-bis(1-amino-4,4-dicyclopropyl-2,3-diaza-1,3-butadienyl). The compound exists in the trans conformation in the solid-state and has a trans population of 91.2% in solution. Experimental data are compared with values estimated by ab initio calculations.
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Source Title
Bulletin of the Chemical Society of Japan
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Date
2001-04
DOI
10.1246/bcsj.74.699
Type
Article