Please use this identifier to cite or link to this item: https://doi.org/10.1002/app.1994.070530701
Title: Complexation between poly(2-hydroxypropyl methacrylate) and three tertiary amide polymers
Authors: Dai, Jie
Goh, S.H. 
Lee, S.Y. 
Siow, K.S. 
Issue Date: 1994
Citation: Dai, Jie, Goh, S.H., Lee, S.Y., Siow, K.S. (1994). Complexation between poly(2-hydroxypropyl methacrylate) and three tertiary amide polymers. Journal of Applied Polymer Science 53 (7) : 837-845. ScholarBank@NUS Repository. https://doi.org/10.1002/app.1994.070530701
Abstract: The complexation behavior between poly(2-hydroxypropyl methacrylate) (PHPMA) and three isomeric tertiary amide polymers, namely, poly(N-methyl-N-vinylacetamide) (PMVAc), poly(N,N-dimethylacrylamide) (PDMA), and poly(2-ethyl-2-oxazoline) (PEOx), was studied. PHPMA forms interpolymer complexes with the three tertiary amide polymers at the entire feed composition range in methyl ethyl ketone and tetrahydrofuran solutions, indicating a strong intermolecular interaction between different polymer chains. However, complexation does not occur between PHPMA and the three tertiary amide polymers in N,N-dimethylformamide solutions. Infrared spectroscopic studies show that the intermolecular hydrogen bonding association between the hydroxyl groups in PHPMA and the amide carbonyl groups in the tertiary amide polymers is stronger than the self-association between the hydroxyl groups and the ester carbonyl groups in PHPMA. PHPMA has a stronger complexation ability with these tertiary amide polymers than poly(styrene-co-allyl alcohol) and poly(hydroxyether of bisphenol-A) do.
Source Title: Journal of Applied Polymer Science
URI: http://scholarbank.nus.edu.sg/handle/10635/75791
ISSN: 00218995
DOI: 10.1002/app.1994.070530701
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