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|Title:||Chiral primary amine mediated conjugate addition of branched aldehydes to vinyl sulfone: Asymmetric generation of quaternary carbon centers|
|Citation:||Zhu, Q., Lu, Y. (2010). Chiral primary amine mediated conjugate addition of branched aldehydes to vinyl sulfone: Asymmetric generation of quaternary carbon centers. Chemical Communications 46 (13) : 2235-2237. ScholarBank@NUS Repository. https://doi.org/10.1039/b919549a|
|Abstract:||Novel l-threonine-derived bifunctional organic catalysts containing primary amine and sulfonamide groups were utilized to promote asymmetric conjugate addition of α,α-disubstitued aldehydes to 1,1-bis(benzenesulfonyl) ethylene. The adducts with quaternary stereogenic centers adjacent to an aldehyde group were obtained in high yield and with good enantioselectivity. © 2010 The Royal Society of Chemistry.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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