Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/75658
Title: Binary blends of poly(3-chloropropyl methacrylate) and poly(2-iodoethyl methacrylate) with aliphatic polyesters
Authors: Low, S.M.
Goh, S.H. 
Lee, S.Y. 
Keywords: aliphatic polyesters
blend miscibility
poly(haloalkyl methacrylate)s
Issue Date: Jul-1994
Citation: Low, S.M.,Goh, S.H.,Lee, S.Y. (1994-07). Binary blends of poly(3-chloropropyl methacrylate) and poly(2-iodoethyl methacrylate) with aliphatic polyesters. Polymer 35 (15) : 3290-3295. ScholarBank@NUS Repository.
Abstract: The miscibility behaviour of poly(3-chloropropyl methacrylate) (PCPMA) and poly(2-iodoethyl methacrylate) (PIEMA) with a series of aliphatic polyesters was investigated by differential scanning calorimetry. Binary blends of PCPMA and PIEMA with poly(butylene adipate), poly(2,2-dimethyl-1,3-propylene adipate), poly(ε-caprolactone) (PCL) and poly(hexamethylene sebacate) (PHS) exhibit single, composition-dependent glass transition temperatures, characteristic of miscible systems. However, PCPMA and PIEMA are immiscible with poly(ethylene succinate), poly(ethylene adipate) and poly(2,2-dimethyl-1,3-propylene succinate). Blends of PCPMA and PIEMA with poly(2,2-dimethyl-1,3-propylene sebacate) exhibit upper critical solution temperature behaviour. Interaction parameters for PCPMA/PHS, PIEMA/PHS, PCPMA/PCL and PIEMA/PCL blends were evaluated from melting-point depression analysis. © 1994.
Source Title: Polymer
URI: http://scholarbank.nus.edu.sg/handle/10635/75658
ISSN: 00323861
Appears in Collections:Staff Publications

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