Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/75632
Title: Asymmetric synthesis of keto-substituted P-chiral phosphines by means of an unusual exo/endo-stereochemically controlled Diels-Alder reaction
Authors: Leung, P.-H. 
Loh, S.-K.
Vittal, J.J. 
White, A.J.P.
Williams, D.J.
Issue Date: 1997
Source: Leung, P.-H.,Loh, S.-K.,Vittal, J.J.,White, A.J.P.,Williams, D.J. (1997). Asymmetric synthesis of keto-substituted P-chiral phosphines by means of an unusual exo/endo-stereochemically controlled Diels-Alder reaction. Chemical Communications (20) : 1987-1988. ScholarBank@NUS Repository.
Abstract: An asymmetric Diels-Alder reaction between 1-phenyl-3,4-dimethylphosphole and ethyl vinyl ketone promoted by a chiral organopalladium complex gives the corresponding keto-substituted phosphine ligands in which the keto group can be stereospecifically located in the endo- or exo-positions of the phosphanorbornene skeleton.
Source Title: Chemical Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/75632
ISSN: 13597345
Appears in Collections:Staff Publications

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