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|Title:||Asymmetric synthesis of keto-substituted P-chiral phosphines by means of an unusual exo/endo-stereochemically controlled Diels-Alder reaction|
|Authors:||Leung, P.-H. |
|Source:||Leung, P.-H.,Loh, S.-K.,Vittal, J.J.,White, A.J.P.,Williams, D.J. (1997). Asymmetric synthesis of keto-substituted P-chiral phosphines by means of an unusual exo/endo-stereochemically controlled Diels-Alder reaction. Chemical Communications (20) : 1987-1988. ScholarBank@NUS Repository.|
|Abstract:||An asymmetric Diels-Alder reaction between 1-phenyl-3,4-dimethylphosphole and ethyl vinyl ketone promoted by a chiral organopalladium complex gives the corresponding keto-substituted phosphine ligands in which the keto group can be stereospecifically located in the endo- or exo-positions of the phosphanorbornene skeleton.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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