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|Title:||Asymmetric synthesis and the novel retro Diels-Alder reaction of a P-chiral sulfonyl-substituted phosphanorbornene|
|Authors:||Leung, P.-H. |
|Source:||Leung, P.-H., Lang, H., Zhang, X., Selvaratnam, S., Vittal, J.J. (2000-07-14). Asymmetric synthesis and the novel retro Diels-Alder reaction of a P-chiral sulfonyl-substituted phosphanorbornene. Tetrahedron Asymmetry 11 (13) : 2661-2664. ScholarBank@NUS Repository. https://doi.org/10.1016/S0957-4166(00)00219-6|
|Abstract:||An asymmetric Diels-Alder reaction between phenylvinylsulfone and 1-phenyl-3,4-dimethylphosphole in the presence of a chiral organometallic reaction promoter generates the corresponding P-chiral sulfonyl-substituted phosphanorbornene which is found to undergo the facile cycloreversion reaction under mild conditions. Copyright (C) 2000 Elsevier Science Ltd.|
|Source Title:||Tetrahedron Asymmetry|
|Appears in Collections:||Staff Publications|
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