Please use this identifier to cite or link to this item:
|Title:||Asymmetric synthesis and the coordination chemistry of a P-chiral diphosphine monoxide|
|Citation:||Teo, T.-W., Selvaratnam, S., Vittal, J.J., Leung, P.-H. (2003-08-06). Asymmetric synthesis and the coordination chemistry of a P-chiral diphosphine monoxide. Inorganica Chimica Acta 352 : 213-219. ScholarBank@NUS Repository. https://doi.org/10.1016/S0020-1693(03)00154-3|
|Abstract:||The organopalladium complex containing ortho-metalated (R)-(1-(dimethylamino)ethyl)-naphthalene as the chiral auxiliary has been used successfully to promote the asymmetric [4+2] exo-cycloaddition reaction between 1-phenyl-3,4-dimethylphosphole and vinyldiphenylphosphine oxide. The resulting P-chiral phosphanorbornene was obtained as a P-O bidenate chelate on the palladium template. The phosphanorbornene (-)-(L) could be liberated from the palladium template as a highly air-sensitive oil by the treatment of the template complex with aqueous potassium cyanide. Upon recoordination to the Au(I) ion, the diphosphine monoxide coordinated to Au(I) as a monodentate ligand via its tertiary phosphorus donor atom to form the linear complex (+)-[(L-P)AuCl]. The chloro ligand and the pendant P=O group in the gold complex showed significant hydrophilicity as they both formed hydrogen bondings to a water molecule. However, the neutral gold complex is not soluble in water. © 2003 Elsevier Science B.V. All rights reserved.|
|Source Title:||Inorganica Chimica Acta|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Aug 14, 2018
WEB OF SCIENCETM
checked on Jul 25, 2018
checked on Aug 17, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.