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http://scholarbank.nus.edu.sg/handle/10635/75621
| Title: | Asymmetric organocatalytic cascade Michael/hemiketalization/retro-Henry reaction of β,γ-unsaturated ketoesters with α-nitroketones |
| Authors: | Gao, Y. Ren, Q. Siau, W.-Y. Wang, J. |
| Issue Date: | 28-May-2011 |
| Citation: | Gao, Y., Ren, Q., Siau, W.-Y., Wang, J. (2011-05-28). Asymmetric organocatalytic cascade Michael/hemiketalization/retro-Henry reaction of β,γ-unsaturated ketoesters with α-nitroketones. Chemical Communications 47 (20) : 5819-5821. ScholarBank@NUS Repository. |
| Abstract: | An unprecedented enantioselective organocatalytic Michael/hemiketalization/ retro-Henry cascade sequence is described, which catalyzed by a simple bifunctional indane amine-thiourea catalyst. This process provides a new route to the enantioselective synthesis of 5-nitro-pent-2-enoates, a precursor to α-ketolactam. © 2011 The Royal Society of Chemistry. |
| Source Title: | Chemical Communications |
| URI: | http://scholarbank.nus.edu.sg/handle/10635/75621 |
| ISSN: | 13597345 |
| Appears in Collections: | Staff Publications |
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