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|Title:||Asymmetric bromolactonization using amino-thiocarbamate catalyst|
|Citation:||Zhou, L., Tan, C.K., Jiang, X., Chen, F., Yeung, Y.-Y. (2010-11-10). Asymmetric bromolactonization using amino-thiocarbamate catalyst. Journal of the American Chemical Society 132 (44) : 15474-15476. ScholarBank@NUS Repository. https://doi.org/10.1021/ja1048972|
|Abstract:||A novel amino-thiocarbamate-catalyzed bromolactonization of unsaturated carboxylic acids has been developed. The scope of the reaction is evidenced by 22 examples of γ-lactones with up to 99% yield and 93% ee. The protocol was applied in the enantioselective synthesis of the key intermediates of VLA-4 antagonists. © 2010 American Chemical Society.|
|Source Title:||Journal of the American Chemical Society|
|Appears in Collections:||Staff Publications|
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