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|Title:||Asymmetric [3+2] annulation of allenes with maleimides catalyzed by dipeptide-derived phosphines: Facile creation of functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers|
|Citation:||Zhao, Q., Han, X., Wei, Y., Shi, M., Lu, Y. (2012-01-25). Asymmetric [3+2] annulation of allenes with maleimides catalyzed by dipeptide-derived phosphines: Facile creation of functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers. Chemical Communications 48 (7) : 970-972. ScholarBank@NUS Repository. https://doi.org/10.1039/c2cc16904e|
|Abstract:||d-Threonine-l-tert-leucine-derived bifunctional phosphine, Cat. 11, catalyzed highly enantioselective [3+2] annulation of maleimides with allenes has been disclosed, allowing the synthesis of optically active functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers in good to high yields along with good to high enantioselectivities. © 2012 The Royal Society of Chemistry.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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