Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/75543
Title: Alkoxy isothiocyanates, RO-N=C=S
Authors: Bech, A.T.
Flammang, R.
Pedersen, C.Th.
Wong, M.W. 
Wentrup, C.
Issue Date: Sep-1999
Source: Bech, A.T.,Flammang, R.,Pedersen, C.Th.,Wong, M.W.,Wentrup, C. (1999-09). Alkoxy isothiocyanates, RO-N=C=S. Journal of the Chemical Society. Perkin Transactions 2 (9) : 1869-1873. ScholarBank@NUS Repository.
Abstract: Methoxy isothiocyanate has been identified as a product of pyrolysis of the silver salt of N-methoxydithiocarbamic acid. It is also formed on FVT of 1-(N-methoxythiocarbamoyl)imidazole and 1-(N-methoxythiocarbamoyl)-1,2,4-triazole. Methoxy isothiocyanate was identified by IR spectroscopy in argon matrices at 10 K supported by good agreement with the ab initio and DFT calculated spectrum. Isopropoxy isothiocyanate was generated from the corresponding silver salt in a similar manner. The oligomerization of MeONCS to trithiolanes and tetrathianes is also described.
Source Title: Journal of the Chemical Society. Perkin Transactions 2
URI: http://scholarbank.nus.edu.sg/handle/10635/75543
ISSN: 03009580
Appears in Collections:Staff Publications

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