Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.jorganchem.2012.02.017
DC Field | Value | |
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dc.title | Addition of pyrroles onto terminal alkynes catalyzed by a dinuclear ruthenium (II) complex | |
dc.contributor.author | Tan, S.T. | |
dc.contributor.author | Teo, Y.C. | |
dc.contributor.author | Fan, W.Y. | |
dc.date.accessioned | 2014-06-23T05:31:26Z | |
dc.date.available | 2014-06-23T05:31:26Z | |
dc.date.issued | 2012-06-15 | |
dc.identifier.citation | Tan, S.T., Teo, Y.C., Fan, W.Y. (2012-06-15). Addition of pyrroles onto terminal alkynes catalyzed by a dinuclear ruthenium (II) complex. Journal of Organometallic Chemistry 708-709 : 58-64. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2012.02.017 | |
dc.identifier.issn | 0022328X | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/75526 | |
dc.description.abstract | The addition of pyrroles onto alkynes has been catalyzed by a dinuclear ruthenium complex, Ru2(CO)4(PPh3)2Br4, resulting in the formation of geminal 2-vinylpyrroles in high yields under mild conditions. Further functionalization with pyrroles or alkynes to afford dipyrrolmethanes or 2,5-bis(vinyl)pyrroles via the vinyl functional group can readily be achieved. A mechanism involving cationic ruthenium complexes was proposed based on the product regioselectivity, deuteration and infrared spectroscopic studies carried out on the catalytic process. © 2012 Published by Elsevier B.V. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2012.02.017 | |
dc.source | Scopus | |
dc.subject | Alkynes | |
dc.subject | Hydroarylation | |
dc.subject | Pyrrole | |
dc.subject | Ruthenium complexes | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1016/j.jorganchem.2012.02.017 | |
dc.description.sourcetitle | Journal of Organometallic Chemistry | |
dc.description.volume | 708-709 | |
dc.description.page | 58-64 | |
dc.description.coden | JORCA | |
dc.identifier.isiut | 000302935900008 | |
Appears in Collections: | Staff Publications |
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