Please use this identifier to cite or link to this item:
|Title:||Addition of pyrroles onto terminal alkynes catalyzed by a dinuclear ruthenium (II) complex|
|Citation:||Tan, S.T., Teo, Y.C., Fan, W.Y. (2012-06-15). Addition of pyrroles onto terminal alkynes catalyzed by a dinuclear ruthenium (II) complex. Journal of Organometallic Chemistry 708-709 : 58-64. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2012.02.017|
|Abstract:||The addition of pyrroles onto alkynes has been catalyzed by a dinuclear ruthenium complex, Ru2(CO)4(PPh3)2Br4, resulting in the formation of geminal 2-vinylpyrroles in high yields under mild conditions. Further functionalization with pyrroles or alkynes to afford dipyrrolmethanes or 2,5-bis(vinyl)pyrroles via the vinyl functional group can readily be achieved. A mechanism involving cationic ruthenium complexes was proposed based on the product regioselectivity, deuteration and infrared spectroscopic studies carried out on the catalytic process. © 2012 Published by Elsevier B.V.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Mar 20, 2019
WEB OF SCIENCETM
checked on Mar 5, 2019
checked on Mar 9, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.