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|Title:||A simple route to a novel enantiomerically pure P-chiral phosphine ligand containing a tertiary amide functional group|
|Authors:||Leung, P.-H. |
|Source:||Leung, P.-H.,Loh, S.-K.,Mok, K.F.,White, A.J.P.,Williams, D.J. (1996). A simple route to a novel enantiomerically pure P-chiral phosphine ligand containing a tertiary amide functional group. Chemical Communications (5) : 591-592. ScholarBank@NUS Repository.|
|Abstract:||A new palladium(II) complex containing an amido-substituted P-chiral phosphine ligand is prepared efficiently by the asymmetric Diels-Alder reaction between N,N-dimethylacrylamide and 1-phenyl-3,4-dimethylphosphole; the chelating properties of the functionalised ligand and the absolute configurations of the four newly generated stereocentres are determined by single-crystal X-ray analysis, and the optically active phosphine ligand displaced from the palladium template with 1,2-bis(diphenylphosphino)ethane.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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