Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/75487
Title: A simple route to a novel enantiomerically pure P-chiral phosphine ligand containing a tertiary amide functional group
Authors: Leung, P.-H. 
Loh, S.-K.
Mok, K.F. 
White, A.J.P.
Williams, D.J.
Issue Date: 1996
Source: Leung, P.-H.,Loh, S.-K.,Mok, K.F.,White, A.J.P.,Williams, D.J. (1996). A simple route to a novel enantiomerically pure P-chiral phosphine ligand containing a tertiary amide functional group. Chemical Communications (5) : 591-592. ScholarBank@NUS Repository.
Abstract: A new palladium(II) complex containing an amido-substituted P-chiral phosphine ligand is prepared efficiently by the asymmetric Diels-Alder reaction between N,N-dimethylacrylamide and 1-phenyl-3,4-dimethylphosphole; the chelating properties of the functionalised ligand and the absolute configurations of the four newly generated stereocentres are determined by single-crystal X-ray analysis, and the optically active phosphine ligand displaced from the palladium template with 1,2-bis(diphenylphosphino)ethane.
Source Title: Chemical Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/75487
ISSN: 13597345
Appears in Collections:Staff Publications

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