Please use this identifier to cite or link to this item: https://doi.org/10.1021/jo0303315
Title: A Domino Ring-Opening/Epoxidation of 1,2-Dioxines
Authors: Greatrex, B.W.
Taylor, D.K.
Tiekink, E.R.T. 
Issue Date: 2-Apr-2004
Citation: Greatrex, B.W., Taylor, D.K., Tiekink, E.R.T. (2004-04-02). A Domino Ring-Opening/Epoxidation of 1,2-Dioxines. Journal of Organic Chemistry 69 (7) : 2580-2583. ScholarBank@NUS Repository. https://doi.org/10.1021/jo0303315
Abstract: When allowed to react with alkaline hydrogen peroxide, monocyclic 1,2-dioxines ring-open to their isomeric γ-hydroxyenone intermediates which are rapidly epoxidized to afford trans-4-hydroxy-2,3-epoxyketones in 21-81% yield. In the case of meso-1,2-dioxines, Co(II) complex catalyzed asymmetric ring-opening of the 1,2-dioxine may be employed to furnish enantioenriched epoxides.
Source Title: Journal of Organic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/75409
ISSN: 00223263
DOI: 10.1021/jo0303315
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