Please use this identifier to cite or link to this item:
|Title:||Elastic properties of a polyethylene single-molecule|
|Citation:||Lim, T.-C. (2003-11). Elastic properties of a polyethylene single-molecule. Journal of Mathematical Chemistry 34 (3-4) : 215-220. ScholarBank@NUS Repository. https://doi.org/10.1023/B:JOMC.0000004070.49165.fe|
|Abstract:||Analytical closed-form solution of the elastic properties (such as longitudinal stiffness, shear stiffness and Poisson's ratio) of a taut polyethylene single-molecule is developed in this paper in terms of C-C and C-C-C bond parameters. The concepts considered herein include resolution of forces and of displacement, with due application of Hooke's law to determine the longitudinal stiffness and the in-plane Poisson's ratio. Adopting the solid mechanics theory as an analogy, the shear stiffness of a taut polyethylene chain is conveniently obtained. Results reveal unique Poisson's ratio property of a polyethylene single-molecule in comparison to usual bulk materials, thereby suggesting size-dependency of nano-scale materials in terms of the Poisson's ratio. Finally some frequently occurring terms in all three elastic property expressions are grouped to summarize and to reveal some form of uniformity in the analytical solutions.|
|Source Title:||Journal of Mathematical Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Oct 17, 2018
WEB OF SCIENCETM
checked on Oct 9, 2018
checked on Sep 29, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.