Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/67556
Title: Static SIMS of conjugated polymers: films of the substituted polyacetylenes
Authors: Huan, C.H.A. 
Wee, A.T.S. 
Gopalakrishnan, R. 
Tan, K.L. 
Kang, E.T. 
Neoh, K.G. 
Liaw, D.J.
Issue Date: Jan-1993
Source: Huan, C.H.A.,Wee, A.T.S.,Gopalakrishnan, R.,Tan, K.L.,Kang, E.T.,Neoh, K.G.,Liaw, D.J. (1993-01). Static SIMS of conjugated polymers: films of the substituted polyacetylenes. Synthetic Metals 53 (2) : 193-203. ScholarBank@NUS Repository.
Abstract: The static secondary ion mass spectroscopic (SIMS) spectra of some environmentally stable substituted derivatives of polyacetylene, such as poly(phenylacetylene), poly(1-phenyl-1-propyne), poly(1-chloro-2-phenylacetylene), poly((o-trimethylsilyl)-phenyl)-acetylene) and poly(t-butylacetylene), have been examined. Structural differences among the polymers are reflected in the spectra and are compared with previous work on the partially unsaturated aliphatic polymers. The presence of strongly ionic elements such as Si and Cl in the polymer structure alters the ionization of fragments. The static SIMS spectra are also compared with those of polystyrene which has a saturated hydrocarbon backbone. An attempt is made to account for the effect of chain conjugation and substituents on the various polymer spectra. © 1993.
Source Title: Synthetic Metals
URI: http://scholarbank.nus.edu.sg/handle/10635/67556
ISSN: 03796779
Appears in Collections:Staff Publications

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