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|Title:||Nanostructured thermoresponsive quantum dot/PNIPAM assemblies|
Reversible switching of luminescence
Stimuli responsive polymer
|Citation:||Tagit, O., Jańczewski, D., Tomczak, N., Han, M.Y., Herek, J.L., Vancso, G.J. (2010-07). Nanostructured thermoresponsive quantum dot/PNIPAM assemblies. European Polymer Journal 46 (7) : 1397-1403. ScholarBank@NUS Repository. https://doi.org/10.1016/j.eurpolymj.2010.04.026|
|Abstract:||Synthesis, characterization, and applications of novel thermoresponsive polymeric coatings for quantum dots (QDs) are presented. Comb-copolymers featuring hydrophobic alkyl groups, carboxylic groups and poly(N-isopropylacrylamide) (PNIPAM) side chains with molar masses ranging from 1000 g/mol to 25,400 g/mol were obtained. The amphiphilic comb-copolymers were shown to efficiently transfer the QDs to aqueous media. The PNIPAM-coated QD materials display a lower critical solution temperature (LCST). The absorbance, luminescence emission, size of the assemblies, and electrophoretic mobility were followed as a function of temperature and the reversibility of the temperature induced changes is demonstrated by cyclic heating and cooling. © 2010 Elsevier Ltd. All rights reserved.|
|Source Title:||European Polymer Journal|
|Appears in Collections:||Staff Publications|
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