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|Title:||Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid: Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations|
|Source:||Wu, N., Feng, S.S., Chiew, Y.C. (2003-06-15). Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid: Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations. Journal of Chemical Physics 118 (23) : 10794-10807. ScholarBank@NUS Repository. https://doi.org/10.1063/1.1575199|
|Abstract:||The multi-density Ornstein-Zernike (MOZ) integral equation theory was used to model a homonuclear sticky hard sphere (SHS) chain fluid in the context of the polymer Percus-Yevick (PPY) and ideal chain approximations. It was found that for a nonathermal system, the difference of structural properties between a monodisperse and a polydisperse system is not of significance only at intermediate and high densities. The Helmholtz energy, pressure, and phase coexistence of the monodisperse SHS chains were computed via the energy route.|
|Source Title:||Journal of Chemical Physics|
|Appears in Collections:||Staff Publications|
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