Please use this identifier to cite or link to this item: https://doi.org/10.1021/jp0654967
Title: Theoretical investigation of substrate effect on deliquescence relative humidity of NaCl particles
Authors: Gao, Y.
Yu, L.E. 
Chen, S.B. 
Issue Date: 1-Feb-2007
Citation: Gao, Y., Yu, L.E., Chen, S.B. (2007-02-01). Theoretical investigation of substrate effect on deliquescence relative humidity of NaCl particles. Journal of Physical Chemistry A 111 (4) : 633-639. ScholarBank@NUS Repository. https://doi.org/10.1021/jp0654967
Abstract: A theoretical investigation is conducted for the first time to explore the deliquescence of particles deposited on a substrate. The formulation incorporates the Kelvin effect with the assumption that the dry and wet particles are both spherical caps in shape. Unlike the deposited particles larger than 500 nm, the deliquescence relative humidity (DRH) of smaller particles can substantially depend on the particle size, the contact angles, and the surface tension between the particle and the atmosphere. At certain contact angles, small particles depositing on a substrate could deliquesce at a much lower RH, posing a potential corrosion problem for metallic substrates. © 2007 American Chemical Society.
Source Title: Journal of Physical Chemistry A
URI: http://scholarbank.nus.edu.sg/handle/10635/64723
ISSN: 10895639
DOI: 10.1021/jp0654967
Appears in Collections:Staff Publications

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