Please use this identifier to cite or link to this item:
|Title:||Synthesis of highly fluorescent metal (Ag, Au, Pt, and Cu) nanoclusters by electrostatically induced reversible phase transfer|
|Citation:||Yuan, X., Luo, Z., Zhang, Q., Zhang, X., Zheng, Y., Lee, J.Y., Xie, J. (2011-11-22). Synthesis of highly fluorescent metal (Ag, Au, Pt, and Cu) nanoclusters by electrostatically induced reversible phase transfer. ACS Nano 5 (11) : 8800-8808. ScholarBank@NUS Repository. https://doi.org/10.1021/nn202860s|
|Abstract:||This paper reports a simple and scalable method for the synthesis of highly fluorescent Ag, Au, Pt, and Cu nanoclusters (NCs) based on a mild etching environment made possible by phase transfer via electrostatic interactions. Using Ag as a model metal, a simple and fast (total synthesis time < 3 h) phase transfer cycle (aqueous → organic (2 h incubation) → aqueous) has been developed to process originally polydisperse, nonfluorescent, and unstable Ag NCs into monodisperse, highly fluorescent, and extremely stable Ag NCs in the same phase (aqueous) and protected by the same thiol ligand. The synthetic protocol was successfully extended to fabricate highly fluorescent Ag NCs protected by custom-designed peptides with desired functionalities (e.g., carboxyl, hydroxyl, and amine). The facile synthetic method developed in this study should largely contribute to the practical applications of this new class of fluorescence probes. © 2011 American Chemical Society.|
|Source Title:||ACS Nano|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jul 14, 2018
WEB OF SCIENCETM
checked on Jul 4, 2018
checked on Jun 8, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.