Please use this identifier to cite or link to this item: https://doi.org/10.1002/ejic.200501049
Title: Aminoethyl-functionalized cyclopentadienyliridium complexes: Photochemical C-H activation and carbonylation of cycloalkanes
Authors: Pek, K.C.
Weng, K.L. 
Krummel, K.I.
Garland, M.V. 
Keywords: C-H activation
Carbonylation
Cyclopentadienyl ligands
Iridium
Photochemistry
Issue Date: 13-Apr-2006
Source: Pek, K.C., Weng, K.L., Krummel, K.I., Garland, M.V. (2006-04-13). Aminoethyl-functionalized cyclopentadienyliridium complexes: Photochemical C-H activation and carbonylation of cycloalkanes. European Journal of Inorganic Chemistry (8) : 1568-1572. ScholarBank@NUS Repository. https://doi.org/10.1002/ejic.200501049
Abstract: The photochemical C-H activation of cycloalkanes by aminoethyl-functionalized cyclopentadienyliridium complexes proceeds in a broadly similar way to that for their unfunctionalized analogues. In a carbon monoxide atmosphere, there is evidence that carbonylation to form the carboxaldehyde occurred with both systems. In situ infrared spectroscopic studies on these reactions allow the identification of several species present in low concentrations in the reaction mixture. © Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
Source Title: European Journal of Inorganic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/63456
ISSN: 14341948
DOI: 10.1002/ejic.200501049
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