Please use this identifier to cite or link to this item: https://doi.org/10.1063/1.2360925
Title: On the thermodynamic modeling of the isosteric heat of adsorption and comparison with experiments
Authors: Chakraborty, A.
Saha, B.B.
Koyama, S.
Ng, K.C. 
Issue Date: 2006
Source: Chakraborty, A., Saha, B.B., Koyama, S., Ng, K.C. (2006). On the thermodynamic modeling of the isosteric heat of adsorption and comparison with experiments. Applied Physics Letters 89 (17) : -. ScholarBank@NUS Repository. https://doi.org/10.1063/1.2360925
Abstract: A theoretical framework for the estimation of the isosteric heat of adsorption between an adsorbate (vapor) and an adsorbent (solid) is proposed based on the thermodynamic requirements of chemical equilibrium, Maxwell relations, and the entropy of the adsorbed phase. The derived equation for the isosteric heat of adsorption is verified against three sets of judiciously selected adsorbent+adsorbate data that are found in the literature and the predictions are found to agree within the experimental uncertainties of the reported data. © 2006 American Institute of Physics.
Source Title: Applied Physics Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/60999
ISSN: 00036951
DOI: 10.1063/1.2360925
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