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|Title:||Organocatalytic Michael addition of aldehydes to vinyl sulfones: Enantioselective α-alkylations of aldehydes and their derivatives|
|Citation:||Zhu, Q., Lu, Y. (2008). Organocatalytic Michael addition of aldehydes to vinyl sulfones: Enantioselective α-alkylations of aldehydes and their derivatives. Organic Letters 10 (21) : 4803-4806. ScholarBank@NUS Repository. https://doi.org/10.1021/ol8019296|
|Abstract:||(Equation Presented) Organocatalytic asymmetric Michael reaction of unmodified aldehydes to vinyl sulfones catalyzed by silylated biarylprolinol afforded the desired Michael products with exceptional enantioselectivity. The described enantioselective addition to vinyl sulfones, in combination with desulfonation, offers a unique, asymmetric entry to α-alkylated aldehydes and their derivatives. © 2008 American Chemical Society.|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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