Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201305348
Title: Tetracyanoquaterrylene and tetracyanohexarylenequinodimethanes with tunable ground states and strong near-infrared absorption
Authors: Zeng, Z.
Lee, S.
Zafra, J.L.
Ishida, M.
Zhu, X.
Sun, Z.
Ni, Y.
Webster, R.D.
Li, R.-W.
López Navarrete, J.T.
Chi, C. 
Ding, J. 
Casado, J.
Kim, D.
Wu, J. 
Keywords: biradicaloids
hexarylene
near-infrared dyes
polycyclic hydrocarbons
quaterrylene
Issue Date: 12-Aug-2013
Source: Zeng, Z.,Lee, S.,Zafra, J.L.,Ishida, M.,Zhu, X.,Sun, Z.,Ni, Y.,Webster, R.D.,Li, R.-W.,López Navarrete, J.T.,Chi, C.,Ding, J.,Casado, J.,Kim, D.,Wu, J. (2013-08-12). Tetracyanoquaterrylene and tetracyanohexarylenequinodimethanes with tunable ground states and strong near-infrared absorption. Angewandte Chemie - International Edition 52 (33) : 8561-8565. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201305348
Abstract: Biradicaloids based on quinoidal rylenes! Soluble and stable tetracyanoquaterrylenequinodimethane (QR-CN) and tetracyanohexarylenequinodimethane (HR-CN) were synthesized. QR-CN has a closed-shell quinoidal structure in the ground state, whereas HR-CN has a singlet biradical ground state. Both compounds showed very strong one-photon and two-photon absorption in the NIR range. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/52634
ISSN: 14337851
DOI: 10.1002/anie.201305348
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