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| Title: | Photoelectron spectroscopy and substituent effects in halonaphthalenes | Authors: | Novak, I. Harrison, L.J. Li, W. |
Keywords: | Photoelectron spectroscopy Substituent effects |
Issue Date: | 2008 | Citation: | Novak, I., Harrison, L.J., Li, W. (2008). Photoelectron spectroscopy and substituent effects in halonaphthalenes. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 69 (1) : 78-81. ScholarBank@NUS Repository. | Abstract: | The electronic structure of two isomeric dibromonaphthalenes (C10H6Br2) has been investigated by HeI/HeII photoelectron spectroscopy. The spectra were assigned by Green's functions calculations and comparison with the spectra of related dibromobenzenes (C6H4Br2). The analysis of π-orbital and halogen lone pair ionization energies, enabled us to determine the magnitude of bromine-bromine intramolecular interactions and distinguish between through-bond and through-space type interactions. We also discuss the halogen-halogen interactions in other polynuclear aromatics. © 2007 Elsevier B.V. All rights reserved. | Source Title: | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy | URI: | http://scholarbank.nus.edu.sg/handle/10635/24468 | ISSN: | 13861425 |
| Appears in Collections: | Staff Publications |
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