Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/151872
DC Field | Value | |
---|---|---|
dc.title | PART I: SELENOFUNCTIONAL & HALOFUNCTIONALISATION MEDIATED BY CHALCOGENIDE BASED CATALYSTS; PART II: METAL CATALYZED THIOCYANOFUNCTIONALIZATION OF ALKYNES | |
dc.contributor.author | SEE JIE YANG | |
dc.date.accessioned | 2019-02-28T18:11:53Z | |
dc.date.available | 2019-02-28T18:11:53Z | |
dc.date.issued | 2018-08-23 | |
dc.identifier.citation | SEE JIE YANG (2018-08-23). PART I: SELENOFUNCTIONAL & HALOFUNCTIONALISATION MEDIATED BY CHALCOGENIDE BASED CATALYSTS; PART II: METAL CATALYZED THIOCYANOFUNCTIONALIZATION OF ALKYNES. ScholarBank@NUS Repository. | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/151872 | |
dc.description.abstract | This dissertation will comprise of two parts. Part one details on the use of chalcogen-based organocatalysts in halofunctionalization and selenofunctionalization of alkenes. In this part, the difficulties and rationale behind the design and synthesis of novel chalcogen-based organocatalysts are discussed. These catalysts are subsequently used in desymmetrization of diol based alkene substrates and their analogues. Part two will describe the use of metal catalysts, with emphasis on silver and gold salts in enabling thiocyanofunctionalization of alkynes. Whereas halofunctionalization have been extensively explored in the literature, there is scarce research work on its thiocyanate counterpart. This portion serves as an exploratory work on the use of metal catalysts in “planting” thiocyanides on alkynyl substrates. | |
dc.language.iso | en | |
dc.subject | Chalcogen, Asymmetric, Catalysis, Thiocyanate, Selenium, Sulfur | |
dc.type | Thesis | |
dc.contributor.department | CHEMISTRY | |
dc.contributor.supervisor | ZHAO YU | |
dc.description.degree | Ph.D | |
dc.description.degreeconferred | DOCTOR OF PHILOSOPHY | |
dc.identifier.orcid | 0000-0003-1014-190X | |
Appears in Collections: | Ph.D Theses (Open) |
Show simple item record
Files in This Item:
File | Description | Size | Format | Access Settings | Version | |
---|---|---|---|---|---|---|
01 Cover page.pdf | 85.55 kB | Adobe PDF | OPEN | None | View/Download | |
02 Content Page.pdf | 252.4 kB | Adobe PDF | OPEN | None | View/Download | |
03 Chapter 1.pdf | 996.3 kB | Adobe PDF | OPEN | None | View/Download | |
04 Chapter 2.pdf | 5.16 MB | Adobe PDF | OPEN | None | View/Download | |
05 Chapter 3.pdf | 606.2 kB | Adobe PDF | OPEN | None | View/Download | |
06 Chapter 4.pdf | 1.19 MB | Adobe PDF | OPEN | None | View/Download |
Google ScholarTM
Check
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.