Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/14936
Title: Cyclometalated-amine template promoted asymmetric synthesis of chiral phosphines and their metal complexes
Authors: YEO WEE CHUAN
Keywords: cyclometalated-amine template, functionalized chiral phosphines, asymmetric synthesis, Diels-Alder, hydrophosphination, [2+2] cycloaddition
Issue Date: 26-Sep-2005
Source: YEO WEE CHUAN (2005-09-26). Cyclometalated-amine template promoted asymmetric synthesis of chiral phosphines and their metal complexes. ScholarBank@NUS Repository.
Abstract: This thesis describes the development of chiral cyclometalated-amine template promoted asymmetric reactions such as the Diels-Alder reaction, [2+2] cycloaddition reaction and the hydrophosphination reaction for the synthesis of chiral phosphines and their metal complexes. Organic transformations on the chiral phosphines with metal protection are also demonstrated, which can serve as an alternative general route for the synthesis of functionalized chiral phosphine ligands and metal complexes.
URI: http://scholarbank.nus.edu.sg/handle/10635/14936
Appears in Collections:Ph.D Theses (Open)

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References.pdf152.84 kBAdobe PDF

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Publications.pdf13.01 kBAdobe PDF

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